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Gas laws and the kinetic modelPressure and volume of a gas

The behaviour of gases is described in terms of the kinetic theory, which considers the motion of molecules in the gas. The gas law links pressure, volume and temperature.

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Pressure and volume of a gas

Boyle's Law

Imagine a gas is trapped in a cylinder by a piston.

If the piston is pushed in, the gas particles will have less room to move as the volume the gas occupies has been decreased.

Process of equilibrium

Piston prior to being pushed in and piston pushed into cylinder.

Two containers: the first has a plunger at the top with two arrows above it labelled 'Pressure (P1)' pointing downwards, while beneath the plunger there are red particles spread apart in a large area labelled 'Volume (V1)'. The second shows the plunger depressed further into the container with 4 arrows above labelled 'Pressure (P2). The same particles are now compressed in a much smaller area at the bottom of the container labelled 'Volume (V2)'.

Because there has been a decrease in volume the particles will collide more frequently with the walls of the container. Each time they collide with the walls, they exert a force on them. More collisions mean more force, so the pressure will increase.

When the volume decreases the pressure increases. This shows that the pressure of a gas is to its volume.

From this we can derive the following equation:

\({p_1}{V_1} = {p_2}{V_2} \) (Sometimes known as Boyle's Law)

where

  • \(p_{1}\) is the starting pressure (measured in any relevant unit of pressure, eg pascals)
  • \(V_{1}\) is the starting volume (measured in any relevant unit of volume, eg litres)
  • \(p_{2}\) is the finishing pressure (must be measured in the same units as \(p_{1}\)
  • \(V_{2}\) is the finishing volume (must be measured in the same units as \(V_{1}\))

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